An unprecedented direct oxidation of high-oleic triglycerides to produce azelaic glycerides has been carried out by using a catalytic system based on H2WO4/H2O2. The results are highly competitive with those reported so far for simpler feedstock: at low catalyst loading the oxidation proceeds with satisfactory yields also starting from a real waste oil matrix without any prior purification.

Direct and Solvent-Free Oxidative Cleavage of Double Bonds in High-Oleic Vegetable Oils

Melchiorre M.;Cucciolito M. E.;Melchiorre C.;Ruffo F.
;
Esposito R.
2020

Abstract

An unprecedented direct oxidation of high-oleic triglycerides to produce azelaic glycerides has been carried out by using a catalytic system based on H2WO4/H2O2. The results are highly competitive with those reported so far for simpler feedstock: at low catalyst loading the oxidation proceeds with satisfactory yields also starting from a real waste oil matrix without any prior purification.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11588/806967
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