The excess enthalpies, free energies and entropies of aqueous solution of some 2-deoxy-sugars have been determined at 298.15 K by microcalorimetric and isopiestic measurements. The differences between the thermodynamic properties of these 2-deoxy-derivatives resemble those that characterize the parent monosaccharides and seem to depend on the solute stereochemistry. In order to obtain information about the conformational analogies between the deoxy-derivatives and their parent monosaccharides, a crystallographic study and nmr investigation in solution are also in advance on these compounds. © 1985.
Thermodynamic and spectroscopic properties of 2-deoxy-sugars in water. Comparison with the crystal structures / G., Barone; Castronuovo, Giuseppina; V., Elia; Mattia, Carlo; R., Puliti; R., Rizzo. - In: THERMOCHIMICA ACTA. - ISSN 0040-6031. - ELETTRONICO. - 85:(1985), pp. 451-454.
Thermodynamic and spectroscopic properties of 2-deoxy-sugars in water. Comparison with the crystal structures.
CASTRONUOVO, GIUSEPPINA;MATTIA, CARLO;
1985
Abstract
The excess enthalpies, free energies and entropies of aqueous solution of some 2-deoxy-sugars have been determined at 298.15 K by microcalorimetric and isopiestic measurements. The differences between the thermodynamic properties of these 2-deoxy-derivatives resemble those that characterize the parent monosaccharides and seem to depend on the solute stereochemistry. In order to obtain information about the conformational analogies between the deoxy-derivatives and their parent monosaccharides, a crystallographic study and nmr investigation in solution are also in advance on these compounds. © 1985.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
