Enthalpies of dilution in water of binary aqueous solutions of n-diols of increasing alkyl chain length are performed using a flow microcalorimeter. The pairwise enthalpic coefficients of these hydrophobic solutes depend mainly on the mutual positions of the -OH groups in the molecule. A rationalization of the excess enthalpies of positional isomers is attempted.
Hydrophobic interactions of alkanols. A calorimetric study in water at 298.15 K / C., Cascella; Castronuovo, Giuseppina; V., Elia; R., Sartorio; S., Wurzburger. - In: JOURNAL OF THE CHEMICAL SOCIETY. FARADAY TRANSACTIONS. - ISSN 0956-5000. - ELETTRONICO. - 86:(1990), pp. 85-88. [10.1039/FT9908600085]
Hydrophobic interactions of alkanols. A calorimetric study in water at 298.15 K
CASTRONUOVO, GIUSEPPINA;
1990
Abstract
Enthalpies of dilution in water of binary aqueous solutions of n-diols of increasing alkyl chain length are performed using a flow microcalorimeter. The pairwise enthalpic coefficients of these hydrophobic solutes depend mainly on the mutual positions of the -OH groups in the molecule. A rationalization of the excess enthalpies of positional isomers is attempted.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
