Herein, we report a new strategy for the synthesis of oligosaccharides containing enantiopure L-hexoses. Key for the success of this approach is the use of alfa-L- and beta-L-sugar derivatives, whose preparation through a “domino” reaction starting from the dithiin containing system has already been at the core of previous studies on the synthesis of the whole series of L-hexoses.
Access to unnatural oligosaccharides under mild glycosidation conditions / D'Alonzo, Daniele; Guaragna, Annalisa; Dell’Isola, A.; Palumbo, Giovanni. - (2011). (Intervento presentato al convegno 16th European Carbohydrate Symposium (EUROCARB) tenutosi a Sorrento (NA) nel 3-7 Luglio 2011).
Access to unnatural oligosaccharides under mild glycosidation conditions
D'ALONZO, DANIELE;GUARAGNA, ANNALISA;PALUMBO, GIOVANNI
2011
Abstract
Herein, we report a new strategy for the synthesis of oligosaccharides containing enantiopure L-hexoses. Key for the success of this approach is the use of alfa-L- and beta-L-sugar derivatives, whose preparation through a “domino” reaction starting from the dithiin containing system has already been at the core of previous studies on the synthesis of the whole series of L-hexoses.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
