Synthesis of natural bicyclic and tricyclic diterpenoid diacylglycerols has been performed by regioselective coupling of terpenoid acid with glycerol at 10-sn position. This method may be considered a general approach to obtain optically active acylglycerols. The preparation of 13C-labelled geranylgeranoic acid glyceryl esters is also described here.
Synthetic Studies on Natural Diterpenoid Glyceryl Esters / Ungur, N.; Gavagnin, M.; Fontana, A; Cimino, G.. - In: TETRAHEDRON. - ISSN 0040-4020. - 56:(2000), pp. 2503-2512. [S0040-4020(00)00097-1]
Synthetic Studies on Natural Diterpenoid Glyceryl Esters
Fontana A;
2000
Abstract
Synthesis of natural bicyclic and tricyclic diterpenoid diacylglycerols has been performed by regioselective coupling of terpenoid acid with glycerol at 10-sn position. This method may be considered a general approach to obtain optically active acylglycerols. The preparation of 13C-labelled geranylgeranoic acid glyceryl esters is also described here.File in questo prodotto:
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