Thermal conversion of furan endo‐peroxide I, obtained by photosensitized oxidation of furan II, yields very similar results to those of the oxidation of the furan II by thermally generated singlet oxygen, showing that also in the latter case the endo‐peroxide I is the key intermediate. A mechanistic interpretation of the furan II‐singlet oxygen reaction is reported. Copyright © 1981 Journal of Heterocyclic Chemistry
Photosensitized oxidation of furans. III. Comparison between photochemically and thermally generated singlet oxygen oxidation of 3‐methoxycarbonyl‐2‐methyl‐5‐phenylfuran / Graziano, M. L.; Iesce, M. R.; Carli, B.; Scarpati, R.. - In: JOURNAL OF HETEROCYCLIC CHEMISTRY. - ISSN 0022-152X. - 18:6(1981), pp. 1105-1107. [10.1002/jhet.5570180609]
Photosensitized oxidation of furans. III. Comparison between photochemically and thermally generated singlet oxygen oxidation of 3‐methoxycarbonyl‐2‐methyl‐5‐phenylfuran
Graziano M. L.;Iesce M. R.;
1981
Abstract
Thermal conversion of furan endo‐peroxide I, obtained by photosensitized oxidation of furan II, yields very similar results to those of the oxidation of the furan II by thermally generated singlet oxygen, showing that also in the latter case the endo‐peroxide I is the key intermediate. A mechanistic interpretation of the furan II‐singlet oxygen reaction is reported. Copyright © 1981 Journal of Heterocyclic ChemistryI documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
