The ability to control the energy levels in semiconductors is compelling for optoelectronic applications. In this study, we managed to tune the work function (WF) of halide perovskite semiconductors using self-assembled monolayers of small molecules to induce stable dipoles at the surface. The direction and intensity of the surface dipoles rely on specific molecule-to-surface interactions. Electron acceptor or donor molecules result in the positive or negative WF shifts up to several hundreds of meV. Our approach provides a versatile tool to control the WF of halide perovskite and adjust the energy level alignment at the interface with charge transport materials in perovskite-based optoelectronics. The impact on perovskite solar cells is reported and discussed in detail with the support of modelling.

Tuning halide perovskite energy levels / Canil, L.; Cramer, T.; Fraboni, B.; Ricciarelli, D.; Meggiolaro, D.; Singh, A.; Liu, M.; Rusu, M.; Wolff, C. M.; Phung, N.; Wang, Q.; Neher, D.; Unold, T.; Vivo, P.; Gagliardi, A.; De Angelis, F.; Abate, A.. - In: ENERGY & ENVIRONMENTAL SCIENCE. - ISSN 1754-5692. - 14:3(2021), pp. 1429-1438. [10.1039/d0ee02216k]

Tuning halide perovskite energy levels

Singh A.;Liu M.;Wang Q.;Abate A.
2021

Abstract

The ability to control the energy levels in semiconductors is compelling for optoelectronic applications. In this study, we managed to tune the work function (WF) of halide perovskite semiconductors using self-assembled monolayers of small molecules to induce stable dipoles at the surface. The direction and intensity of the surface dipoles rely on specific molecule-to-surface interactions. Electron acceptor or donor molecules result in the positive or negative WF shifts up to several hundreds of meV. Our approach provides a versatile tool to control the WF of halide perovskite and adjust the energy level alignment at the interface with charge transport materials in perovskite-based optoelectronics. The impact on perovskite solar cells is reported and discussed in detail with the support of modelling.
2021
Tuning halide perovskite energy levels / Canil, L.; Cramer, T.; Fraboni, B.; Ricciarelli, D.; Meggiolaro, D.; Singh, A.; Liu, M.; Rusu, M.; Wolff, C. M.; Phung, N.; Wang, Q.; Neher, D.; Unold, T.; Vivo, P.; Gagliardi, A.; De Angelis, F.; Abate, A.. - In: ENERGY & ENVIRONMENTAL SCIENCE. - ISSN 1754-5692. - 14:3(2021), pp. 1429-1438. [10.1039/d0ee02216k]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11588/857814
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