The mechanism(s) for the formation of syndiotactic PLA by the ROP of meso-LA by a chiral-Al-complex are disclosed by DFT calculations. The contributions toward stereoselectivity have been analyzed confirming the peculiar chiral recognition for stereocontrolled ROP polymerization.
Syndiotactic PLA from meso-LA polymerization at the Al-chiral complex: a probe of DFT mechanistic insights / D'Alterio, M. C.; De Rosa, C.; Talarico, G.. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 57:13(2021), pp. 1611-1614. [10.1039/d0cc07787a]
Syndiotactic PLA from meso-LA polymerization at the Al-chiral complex: a probe of DFT mechanistic insights
D'Alterio M. C.;De Rosa C.;Talarico G.
2021
Abstract
The mechanism(s) for the formation of syndiotactic PLA by the ROP of meso-LA by a chiral-Al-complex are disclosed by DFT calculations. The contributions toward stereoselectivity have been analyzed confirming the peculiar chiral recognition for stereocontrolled ROP polymerization.File in questo prodotto:
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