New ansa-zirconocene with bis(inden-2-yloxy)dimethylsilane ligand was synthesized and characterized by NMR spectroscopy and X-ray crystallography. The zirconocene was found to be highly active catalyst of ethylene polymerization and ethylene/hex-1-ene copolymerization upon methylaluminoxane activation.
Synthesis and olefin polymerization performance of new ansa-zirconocene with OSiO-bridged bis(2-indenyl) ligand / Borisov, I. S.; Mladentsev, D. Y.; Guzeev, B. A.; Goryunov, G. P.; Uborsky, D. V.; Vittoria, A.; Cipullo, R.; Busico, V.; Friederichs, N.; Voskoboynikov, A. Z.. - In: MENDELEEV COMMUNICATIONS. - ISSN 0959-9436. - 30:4(2020), pp. 449-452. [10.1016/j.mencom.2020.07.014]
Synthesis and olefin polymerization performance of new ansa-zirconocene with OSiO-bridged bis(2-indenyl) ligand
Vittoria A.;Cipullo R.;Busico V.;
2020
Abstract
New ansa-zirconocene with bis(inden-2-yloxy)dimethylsilane ligand was synthesized and characterized by NMR spectroscopy and X-ray crystallography. The zirconocene was found to be highly active catalyst of ethylene polymerization and ethylene/hex-1-ene copolymerization upon methylaluminoxane activation.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
