Isocyanides insert into gold(III)–hydrogen bonds to give the first examples of gold iminoformyl complexes. The reaction is initiated by catalytic amounts of radicals; DFT calculations indicate that this is an equilibrium reaction driven forward by isocyanide in sufficient excess to trap the Au(II) intermediate.
Isocyanide insertion into Au-H bonds: First gold iminoformyl complexes / Fernandez-Cestau, Julio; Rocchigiani, Luca; Pintus, Anna; Rama, Raquel J.; Budzelaar, Petrus H. M.; Bochmann, Manfred. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 54:81(2018), pp. 11447-11450. [10.1039/c8cc06409a]
Isocyanide insertion into Au-H bonds: First gold iminoformyl complexes
Budzelaar, Petrus H. M.;
2018
Abstract
Isocyanides insert into gold(III)–hydrogen bonds to give the first examples of gold iminoformyl complexes. The reaction is initiated by catalytic amounts of radicals; DFT calculations indicate that this is an equilibrium reaction driven forward by isocyanide in sufficient excess to trap the Au(II) intermediate.File in questo prodotto:
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