Isocyanides insert into gold(III)–hydrogen bonds to give the first examples of gold iminoformyl complexes. The reaction is initiated by catalytic amounts of radicals; DFT calculations indicate that this is an equilibrium reaction driven forward by isocyanide in sufficient excess to trap the Au(II) intermediate.

Isocyanide insertion into Au-H bonds: First gold iminoformyl complexes

Budzelaar, Petrus H. M.;
2018

Abstract

Isocyanides insert into gold(III)–hydrogen bonds to give the first examples of gold iminoformyl complexes. The reaction is initiated by catalytic amounts of radicals; DFT calculations indicate that this is an equilibrium reaction driven forward by isocyanide in sufficient excess to trap the Au(II) intermediate.
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11588/738857
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