he invention relates to a metallocene complexes, I (R1 = C2-​10 alkyl, preferably C3-​10 alkyl, C6-​20 aryl, C7-​20 aralkyl; R2 = H, C1-​10 alkyl; R3, R4, R5, R6 = H, C1-​10 alkyl, C6-​20 aryl, C7-​20 aralkyl groups and wherein R3 and R4, R4 and R5, or R5 and R6 can be connected to form a ring structure; M = Ti, Zr, Hf; X = an anionic ligand to M)​. The invention also relates to a catalyst comprising the reaction product of the metallocene complex and a cocatalyst. Further the invention relates to a (co)​polymn. process of olefinic monomers.

Dihydrocarbyl-silyl-bridged-substituted cyclopentadienyl metallocene complexes for olefin polymerization / Friederichs, Nicolaas Hendrika; Vittoria, Antonio; Cipullo, Roberta; Busico, Vincenzo; Borisov, Ilya; Guzeev, Bogdan A.; Mladentsev, Dmitry Y.; Sharikov, Mikhail I.; Uborsky, Dmitry; Voskoboynikov, Alexander; Coen, Hendriksen. - (2018).

Dihydrocarbyl-silyl-bridged-substituted cyclopentadienyl metallocene complexes for olefin polymerization

Vittoria, Antonio;Cipullo, Roberta;Busico, Vincenzo;
2018

Abstract

he invention relates to a metallocene complexes, I (R1 = C2-​10 alkyl, preferably C3-​10 alkyl, C6-​20 aryl, C7-​20 aralkyl; R2 = H, C1-​10 alkyl; R3, R4, R5, R6 = H, C1-​10 alkyl, C6-​20 aryl, C7-​20 aralkyl groups and wherein R3 and R4, R4 and R5, or R5 and R6 can be connected to form a ring structure; M = Ti, Zr, Hf; X = an anionic ligand to M)​. The invention also relates to a catalyst comprising the reaction product of the metallocene complex and a cocatalyst. Further the invention relates to a (co)​polymn. process of olefinic monomers.
2018
Dihydrocarbyl-silyl-bridged-substituted cyclopentadienyl metallocene complexes for olefin polymerization / Friederichs, Nicolaas Hendrika; Vittoria, Antonio; Cipullo, Roberta; Busico, Vincenzo; Borisov, Ilya; Guzeev, Bogdan A.; Mladentsev, Dmitry Y.; Sharikov, Mikhail I.; Uborsky, Dmitry; Voskoboynikov, Alexander; Coen, Hendriksen. - (2018).
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11588/738528
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus ND
  • ???jsp.display-item.citation.isi??? ND
social impact