In this work, an amino-functionalized, chromium-based metal organic framework (NH2-Cr-MOF) was synthesized, characterized and tested for the adsorption of a hazardous biogas pollutant such as hydrogen chloride. At ambient temperature, NH2-Cr-MOF showed a significantly high HCl equilibrium adsorption capacity. Moreover, HCl adsorption on NH2-Cr-MOF was found to be fully reversible, and the adsorbent was fully regenerated by vacuum treatment at 423 K.
Amino-functionalized, chromium-based metal organic framework as a potential high performance adsorbent for hydrogen chloride / Gargiulo, Nicola; Peluso, Antonio; Aprea, Paolo; Micoli, Luca; Ausiello, Angelo; Turco, Maria; Cioffi, Raffaele; Jannelli, Elio; Caputo, Domenico. - In: ADVANCED SCIENCE LETTERS. - ISSN 1936-6612. - 23:6(2017), pp. 6010-6011. [10.1166/asl.2017.9094]
Amino-functionalized, chromium-based metal organic framework as a potential high performance adsorbent for hydrogen chloride
Gargiulo, Nicola;Peluso, Antonio;Aprea, Paolo;Micoli, Luca;Ausiello, Angelo;Turco, Maria;Cioffi, Raffaele;Caputo, Domenico
2017
Abstract
In this work, an amino-functionalized, chromium-based metal organic framework (NH2-Cr-MOF) was synthesized, characterized and tested for the adsorption of a hazardous biogas pollutant such as hydrogen chloride. At ambient temperature, NH2-Cr-MOF showed a significantly high HCl equilibrium adsorption capacity. Moreover, HCl adsorption on NH2-Cr-MOF was found to be fully reversible, and the adsorbent was fully regenerated by vacuum treatment at 423 K.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
