The diiminepyridine ligand, made famous by Brookhart and Gibson a decade ago through its use in the first iron-containing olefin polymerization catalyst, also displays an amazing variety of ligand-centred reactions, including electron transfer, alkylation, dimerization and deprotonation. The present Perspective summarizes these reactions and also speculates on the links between ligand- and metal-centred reactivity.
Ligand-centred reactivity in diiminepyridine complexes / Knijnenburg, Quinten; Gambarotta, Sandro; Budzelaar, Petrus Henricus Maria. - In: DALTON TRANSACTIONS. - ISSN 1477-9226. - 46(2006), p. 5442-8. [10.1039/b612251e]
Ligand-centred reactivity in diiminepyridine complexes
BUDZELAAR, Petrus Henricus Maria
2006
Abstract
The diiminepyridine ligand, made famous by Brookhart and Gibson a decade ago through its use in the first iron-containing olefin polymerization catalyst, also displays an amazing variety of ligand-centred reactions, including electron transfer, alkylation, dimerization and deprotonation. The present Perspective summarizes these reactions and also speculates on the links between ligand- and metal-centred reactivity.File in questo prodotto:
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