Platinum(II) olefin compounds [PtMe(N,N′-imino,amide)(η2-olefin)] have been found to dimerize spontaneously in solution, yielding dinuclear complexes through an oxidative coupling. The extended conjugation within the molecules produces an intense blue color, and the properties of the compounds have been investigated through NMR spectroscopy, optical measurements, and theoretical calculations. The solid-state structure of a representative compound has been solved.

Oxidative Coupling of Imino, Amide Platinum(II) Complexes Yields Highly Conjugated Blue Dimers

ESPOSITO, ROBERTO;CALVANESE, LUISA;CUCCIOLITO, MARIA ELENA;D'AURIA, GABRIELLA;FALCIGNO, LUCIA;ROVIELLO, GIUSEPPINA;TALARICO, GIOVANNI;RUFFO, FRANCESCO
2017

Abstract

Platinum(II) olefin compounds [PtMe(N,N′-imino,amide)(η2-olefin)] have been found to dimerize spontaneously in solution, yielding dinuclear complexes through an oxidative coupling. The extended conjugation within the molecules produces an intense blue color, and the properties of the compounds have been investigated through NMR spectroscopy, optical measurements, and theoretical calculations. The solid-state structure of a representative compound has been solved.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11588/679677
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