The unique α-(1→7)-bradyrhizoside linkages are constructed for the first time via judicious choice of the glycosylation partners and conditions, thus tetra- and penta-bradyrhizosides relevant to the peculiar O-antigen of Bradyrhizobium are synthesized, which are shown to adopt the defined right-handed helical conformations and to be unable to induce innate immune responses in plants.
Synthesis of Bradyrhizose Oligosaccharides Relevant to the Bradyrhizobium O-Antigen / Li, Wei; Silipo, Alba; Gersby, Lotte Bettina Andersen; Newman, Mari Anne; Molinaro, Antonio; Yu, Biao. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - 56:8(2017), pp. 2092-2096. [10.1002/anie.201610680]
Synthesis of Bradyrhizose Oligosaccharides Relevant to the Bradyrhizobium O-Antigen
SILIPO, ALBA;MOLINARO, ANTONIO;
2017
Abstract
The unique α-(1→7)-bradyrhizoside linkages are constructed for the first time via judicious choice of the glycosylation partners and conditions, thus tetra- and penta-bradyrhizosides relevant to the peculiar O-antigen of Bradyrhizobium are synthesized, which are shown to adopt the defined right-handed helical conformations and to be unable to induce innate immune responses in plants.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
