A synthesized chromium-based metal organic framework (Cr-MOF) was used for the adsorption of halogenated anesthetics, i.e., sevoflurane (SF). Adsorption isotherm and breakthrough experiments involving SF (reference sorbate) and water vapor were measured at 298 K and atmospheric pressure on both Cr-MOF and a commercially used reference adsorbent. The Cr-MOF MIL-101 showed a significantly higher SF adsorption capacity and much higher selectivity relative to water vapor compared to the reference adsorbent. Binary-mixture breakthrough tests demonstrated a “roll-up effect” for SF on the reference adsorbent while no such effect was observed on MIL-101.
Adsorption Behavior of Halogenated Anesthetic and Water Vapor on Cr-Based MOF (MIL-101) Adsorbent. Part I. Equilibrium and Breakthrough Characterizations / Hua, Ye; Gargiulo, Nicola; Peluso, Antonio; Aprea, Paolo; Eić, Mladen; Caputo, Domenico. - In: CHEMIE INGENIEUR TECHNIK. - ISSN 0009-286X. - 88:11(2016), pp. 1730-1738. [10.1002/cite.201600051]
Adsorption Behavior of Halogenated Anesthetic and Water Vapor on Cr-Based MOF (MIL-101) Adsorbent. Part I. Equilibrium and Breakthrough Characterizations
GARGIULO, NICOLA;PELUSO, ANTONIO;APREA, PAOLO;CAPUTO, DOMENICO
2016
Abstract
A synthesized chromium-based metal organic framework (Cr-MOF) was used for the adsorption of halogenated anesthetics, i.e., sevoflurane (SF). Adsorption isotherm and breakthrough experiments involving SF (reference sorbate) and water vapor were measured at 298 K and atmospheric pressure on both Cr-MOF and a commercially used reference adsorbent. The Cr-MOF MIL-101 showed a significantly higher SF adsorption capacity and much higher selectivity relative to water vapor compared to the reference adsorbent. Binary-mixture breakthrough tests demonstrated a “roll-up effect” for SF on the reference adsorbent while no such effect was observed on MIL-101.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
