The main reaction products of the RuO4 oxidation of a number of linear and cyclic alkenes, at - 70 degrees C in acetone-water (5:1) are 1,2-diols, formed in a syn stereospecific manner, and/or alpha-ketols sometimes accompanied by small amounts of scission products, namely aldehydes and/or carboxylic acids; in some cases, 1,3-dioxolane products, formed by condensation of the 1,2-diol and aldehyde materials, are also obtained.
Ruthenium tetraoxide oxidation of alkenes .7. A more complete picture / Albarella, L., Piccialli, V., Smaldone, D., Sica, D.. - In: JOURNAL OF CHEMICAL RESEARCH. - ISSN 0308-2350. - STAMPA. - (1996), pp. 400-401.
Ruthenium tetraoxide oxidation of alkenes .7. A more complete picture
PICCIALLI, VINCENZO;
1996
Abstract
The main reaction products of the RuO4 oxidation of a number of linear and cyclic alkenes, at - 70 degrees C in acetone-water (5:1) are 1,2-diols, formed in a syn stereospecific manner, and/or alpha-ketols sometimes accompanied by small amounts of scission products, namely aldehydes and/or carboxylic acids; in some cases, 1,3-dioxolane products, formed by condensation of the 1,2-diol and aldehyde materials, are also obtained.File in questo prodotto:
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