The reaction of ruthenium tetraoxide with 5α-cholesta-8,14-dien-3β-yl acetate and 5α-cholesta-7,14-dien-3β-yl acetate, performed using equimolar amts. of the oxidant in acetone-water at low temp., gives mainly epoxides.
Reaction of RuO4 with carbon-carbon double bonds. 4. Reaction of sterols containing the 7,14- or 8,14-diene system with ruthenium tetraoxide: formation of epoxysterols / Giordano, F.; Piccialli, Vincenzo; Sica, D.; Smaldone, D.. - In: JOURNAL OF CHEMICAL RESEARCH. - ISSN 0308-2350. - STAMPA. - 2:(1995), pp. 52-53.
Reaction of RuO4 with carbon-carbon double bonds. 4. Reaction of sterols containing the 7,14- or 8,14-diene system with ruthenium tetraoxide: formation of epoxysterols
PICCIALLI, VINCENZO;
1995
Abstract
The reaction of ruthenium tetraoxide with 5α-cholesta-8,14-dien-3β-yl acetate and 5α-cholesta-7,14-dien-3β-yl acetate, performed using equimolar amts. of the oxidant in acetone-water at low temp., gives mainly epoxides.File in questo prodotto:
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