Long-chain alkylamine tetrachloromercurates(II) ((CnH2n+1NH3)2HgCl4, with n = 8-16) show high-enthalpy solid-solid phase transitions at 293-360 K. These are assocd. with the melting of the hydrocarbon parts of the crystal structure while the inorg. layers remain practically unchanged. The behavior of these salts, as compared with that of analogous compds. with different metals, is discussed in terms of the structural parameters of the inorg. layers.

CONFORMATIONAL SOLID-SOLID PHASE-TRANSITIONS IN LONG-CHAIN ALKYLAMMONIUM TETRACHLOROMERCURATES(II)

BUSICO, VINCENZO;VACATELLO, MICHELE
1979

Abstract

Long-chain alkylamine tetrachloromercurates(II) ((CnH2n+1NH3)2HgCl4, with n = 8-16) show high-enthalpy solid-solid phase transitions at 293-360 K. These are assocd. with the melting of the hydrocarbon parts of the crystal structure while the inorg. layers remain practically unchanged. The behavior of these salts, as compared with that of analogous compds. with different metals, is discussed in terms of the structural parameters of the inorg. layers.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11588/495636
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