1,1-Dimethylallene reacts with phenolic substrates in the presence of catalytic amounts of platinum(II) complexes. A regiospecific C-alkenylation takes place, affording o-isopentenylphenols and 2,2-dimethylchromans. Possible reaction mechanisms are also discussed.
Regiospecific alkenylation of phenols by 1,1-dimethylallene promoted by platinum catalysts / De Renzi, A.; Panunzi, A.; Saporito, A.; Vitagliano, Aldo. - In: JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS II. - ISSN 0300-9580. - STAMPA. - (1983), pp. 993-996.
Regiospecific alkenylation of phenols by 1,1-dimethylallene promoted by platinum catalysts
VITAGLIANO, ALDO
1983
Abstract
1,1-Dimethylallene reacts with phenolic substrates in the presence of catalytic amounts of platinum(II) complexes. A regiospecific C-alkenylation takes place, affording o-isopentenylphenols and 2,2-dimethylchromans. Possible reaction mechanisms are also discussed.File in questo prodotto:
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