M r = 436.26, monoclinic, P2~, a = 8.998 (3), b = 8. 133 (4), c= 9.872 (2) A, fl= 106.72 (3) ° , V= 691.9 (5) ,/~3, Z = 2, D m = 2.09, D x = 2.094 g cm -3, 2(Mo Ka) = 0.7107 ,~, /~ = 106.15 cm -1, F(000) = 412, T=298K, R=0.050, R w=0.057 for 1404 reflections. The compound has a trigonal-bipyramidal structure with the CI atoms in apical positions and the bidentate ligand (which coordinates through its ctdiimine units) and ethylene in the equatorial plane. The bidentate ligand is in a cis conformation with some distortion from planarity. The Pt-CI and Pt-olefin bond distances are usual for five-coordinate complexes of Pt".

Structure of Dichloro[ 1,2-ethanedione bis(dimethylhydrazone)](r/-ethylene)platinum(II), [PtC12(C2H4)(C6H14N4)]

MORELLI, GIANCARLO;PAVONE, VINCENZO
1984

Abstract

M r = 436.26, monoclinic, P2~, a = 8.998 (3), b = 8. 133 (4), c= 9.872 (2) A, fl= 106.72 (3) ° , V= 691.9 (5) ,/~3, Z = 2, D m = 2.09, D x = 2.094 g cm -3, 2(Mo Ka) = 0.7107 ,~, /~ = 106.15 cm -1, F(000) = 412, T=298K, R=0.050, R w=0.057 for 1404 reflections. The compound has a trigonal-bipyramidal structure with the CI atoms in apical positions and the bidentate ligand (which coordinates through its ctdiimine units) and ethylene in the equatorial plane. The bidentate ligand is in a cis conformation with some distortion from planarity. The Pt-CI and Pt-olefin bond distances are usual for five-coordinate complexes of Pt".
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11588/486225
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