The geometrical differences between the chain conformations of isotactic and syndiotactic vinyl Polymers in the crystalline state are discussed. A possible conventional nomenclature for these helices is proposed. From the conformational energy maps of isolated chains, it is possible to predict the chain conformations (including the conformations of the side groups) in the crystalline phases of many new syndiotactic vinyl polymers.
On the Chain Conformation of the Syndiotactic Vinyl-polymers / P., Corradini; DE ROSA, Claudio; G., Guerra; B., Pirozzi; V., Venditto. - In: GAZZETTA CHIMICA ITALIANA. - ISSN 0016-5603. - STAMPA. - 122:(1992), pp. 305-313.
On the Chain Conformation of the Syndiotactic Vinyl-polymers
DE ROSA, CLAUDIO;
1992
Abstract
The geometrical differences between the chain conformations of isotactic and syndiotactic vinyl Polymers in the crystalline state are discussed. A possible conventional nomenclature for these helices is proposed. From the conformational energy maps of isolated chains, it is possible to predict the chain conformations (including the conformations of the side groups) in the crystalline phases of many new syndiotactic vinyl polymers.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
