In order to reduce the discrepancies between first-order transition probabilities relevant to inelastic molecular-collision problems as calculated using classical models and the quantum-mechanical results, we investigate the analytic forms available in the two theories for standard model examples and we find a substantial rule able to bring the classical expression to equality with the quantum one, in the WKB approximation.

A symmetrization rule for collision energies in molecular vibrational transitions / Mastrocinque, Giuseppe; J., Quartieri. - In: LETTERE AL NUOVO CIMENTO DELLA SOCIETÀ ITALIANA DI FISICA. - ISSN 0375-930X. - 33:8(1982), pp. 227-232.

A symmetrization rule for collision energies in molecular vibrational transitions

MASTROCINQUE, GIUSEPPE;
1982

Abstract

In order to reduce the discrepancies between first-order transition probabilities relevant to inelastic molecular-collision problems as calculated using classical models and the quantum-mechanical results, we investigate the analytic forms available in the two theories for standard model examples and we find a substantial rule able to bring the classical expression to equality with the quantum one, in the WKB approximation.
1982
A symmetrization rule for collision energies in molecular vibrational transitions / Mastrocinque, Giuseppe; J., Quartieri. - In: LETTERE AL NUOVO CIMENTO DELLA SOCIETÀ ITALIANA DI FISICA. - ISSN 0375-930X. - 33:8(1982), pp. 227-232.
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11588/479228
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 4
  • ???jsp.display-item.citation.isi??? ND
social impact