Reactions of [{N-,N,Cnaphthyl-}HfMe][MeB(C6F5)3] precatalyst with a series of R-olefins have been investigated in order to intercept the active polymerization species generated by an in situ modification of the precursor by insertion of a singlemonomer unit into theHf-CAryl bond.
On the First Insertion of alpha-olefins in Hafnium Pyridyl-Amido Polymerization Catalysts / Zuccaccia, C.; Busico, Vincenzo; Cipullo, Roberta; Talarico, Giovanni; Froese, R. D. J.; Vosejpka, P. C.; Hustad, P. D.; Macchioni, A.. - In: ORGANOMETALLICS. - ISSN 0276-7333. - STAMPA. - 28:(2009), pp. 5445-5458. [10.1021/om900705v]
On the First Insertion of alpha-olefins in Hafnium Pyridyl-Amido Polymerization Catalysts
BUSICO, VINCENZO;CIPULLO, ROBERTA;TALARICO, GIOVANNI;
2009
Abstract
Reactions of [{N-,N,Cnaphthyl-}HfMe][MeB(C6F5)3] precatalyst with a series of R-olefins have been investigated in order to intercept the active polymerization species generated by an in situ modification of the precursor by insertion of a singlemonomer unit into theHf-CAryl bond.File in questo prodotto:
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