“Privileged ligands” are chiral auxiliaries of wide applicability in asymmetric catalysis. In the previous decades, their effective three-dimensional structures have often been reproduced by using building blocks from a “chiral pool”, such as the carbohydrates. This strategy has provided unique ligand moieties which combine the performance of “privileged ligands” with increased flexibility and accessibility. This review gives an overviewof the research within this field, giving emphasis to the best results obtained with each ligand type.

Carbohydrates as building blocks of privileged ligands

BENESSERE, VINCENZO;DEL LITTO, Raffaella;DE ROMA, ANTONELLA;RUFFO, FRANCESCO
2010

Abstract

“Privileged ligands” are chiral auxiliaries of wide applicability in asymmetric catalysis. In the previous decades, their effective three-dimensional structures have often been reproduced by using building blocks from a “chiral pool”, such as the carbohydrates. This strategy has provided unique ligand moieties which combine the performance of “privileged ligands” with increased flexibility and accessibility. This review gives an overviewof the research within this field, giving emphasis to the best results obtained with each ligand type.
File in questo prodotto:
File Dimensione Formato  
CoordChemRev 254, 2010, 390.pdf

non disponibili

Tipologia: Documento in Post-print
Licenza: Accesso privato/ristretto
Dimensione 1.87 MB
Formato Adobe PDF
1.87 MB Adobe PDF   Visualizza/Apri   Richiedi una copia

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11588/367253
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 80
  • ???jsp.display-item.citation.isi??? 78
social impact