A stereoselective procedure for the preparation of non-naturally occurring deoxy iminosugars belonging to L-series has been developed. The synthesis involves the construction of the key intermediate bicycle pyperidine 8, available in few steps by the coupling of the heterocyclic synthon 3 and the readily available Garner aldehyde 4. © 2007 American Chemical Society.
A general approach to the synthesis of 1-deoxy-L-iminosugars / Guaragna, Annalisa; D'Errico, Stefano; D'Alonzo, Daniele; Pedatella, Silvana; Palumbo, Giovanni. - In: ORGANIC LETTERS. - ISSN 1523-7060. - STAMPA. - 9:17(2007), pp. 3473-3476. [10.1021/ol7014847]
A general approach to the synthesis of 1-deoxy-L-iminosugars
GUARAGNA, ANNALISA;D'ERRICO, STEFANO;D'ALONZO, DANIELE;PEDATELLA, SILVANA;PALUMBO, GIOVANNI
2007
Abstract
A stereoselective procedure for the preparation of non-naturally occurring deoxy iminosugars belonging to L-series has been developed. The synthesis involves the construction of the key intermediate bicycle pyperidine 8, available in few steps by the coupling of the heterocyclic synthon 3 and the readily available Garner aldehyde 4. © 2007 American Chemical Society.File in questo prodotto:
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