Three new orthopalladated chromophores based on push-pull pi conjugated ligands have been prepared and characterized. The second order molecular NLO activity has been determined by EFISH measurements giving mu(g)/beta values up to 610 x 10(-48) esu at an incident laser wavelength of 1.907 mum. The X-ray structures of two different polymorphs of one chromophore are also reported and polymorphism is discussed in terms of conformational changes.

Second Order molecular nonlinearities in new orthopalladated push-pull chromophores / Centore, Roberto; A., Fort; Panunzi, Barbara; Roviello, Antonio; Tuzi, Angela. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - STAMPA. - 357:(2004), pp. 913-918.

Second Order molecular nonlinearities in new orthopalladated push-pull chromophores

CENTORE, ROBERTO;PANUNZI, BARBARA;ROVIELLO, ANTONIO;TUZI, ANGELA
2004

Abstract

Three new orthopalladated chromophores based on push-pull pi conjugated ligands have been prepared and characterized. The second order molecular NLO activity has been determined by EFISH measurements giving mu(g)/beta values up to 610 x 10(-48) esu at an incident laser wavelength of 1.907 mum. The X-ray structures of two different polymorphs of one chromophore are also reported and polymorphism is discussed in terms of conformational changes.
2004
Second Order molecular nonlinearities in new orthopalladated push-pull chromophores / Centore, Roberto; A., Fort; Panunzi, Barbara; Roviello, Antonio; Tuzi, Angela. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - STAMPA. - 357:(2004), pp. 913-918.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11588/200925
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