As an alternative to the standard Cossee mechanism, in which olefin insertion involves two sites at a single metal centre, we have investigated a true dinuclear alternative where the chain switches between two different metal centres at each insertion.
Mono- and dinuclear olefin polymerization at aluminium / Budzelaar, Petrus Henricus Maria; Talarico, Giovanni. - STAMPA. - 221:(2001), pp. U668-U668. (Intervento presentato al convegno 221st ACS National Meeting, tenutosi a San Diego, CA, United States nel April 1-5).
Mono- and dinuclear olefin polymerization at aluminium
BUDZELAAR, Petrus Henricus Maria;TALARICO, GIOVANNI
2001
Abstract
As an alternative to the standard Cossee mechanism, in which olefin insertion involves two sites at a single metal centre, we have investigated a true dinuclear alternative where the chain switches between two different metal centres at each insertion.File in questo prodotto:
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