Protection and stabilization of some unstable olefins has been effectively achieved by coordination in live-coordinate [PtClMe(2,9-Me-2-1,10-phenanthroline)(olefin)] complexes. These have been characterized by H-1-NMR spectroscopy and iu the case of [PtClMe(2,9-Me-2-1,10-phenanthroline)(Z-EtCH=CHOH)] by X-ray diffractometry. Chemoselective reactions have been accomplished on the complexes, some of them involving alcoholic or aldehydic functions of the unsaturated ligand
Stabilization of unstable unsatured molecules in five-coordinate TBP complexes of Pt(II): enol, diol and dialdehyde derivatives / DE FELICE, V.; Giordano, F.; Orabona, I.; Tesauro, Diego; Vitagliano, Aldo. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - STAMPA. - 622:1-2(2001), pp. 242-250. [10.1016/S0022-328X(01)00645-3]
Stabilization of unstable unsatured molecules in five-coordinate TBP complexes of Pt(II): enol, diol and dialdehyde derivatives
TESAURO, DIEGO;VITAGLIANO, ALDO
2001
Abstract
Protection and stabilization of some unstable olefins has been effectively achieved by coordination in live-coordinate [PtClMe(2,9-Me-2-1,10-phenanthroline)(olefin)] complexes. These have been characterized by H-1-NMR spectroscopy and iu the case of [PtClMe(2,9-Me-2-1,10-phenanthroline)(Z-EtCH=CHOH)] by X-ray diffractometry. Chemoselective reactions have been accomplished on the complexes, some of them involving alcoholic or aldehydic functions of the unsaturated ligandI documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
