A rigorous reformulation of nonequilibrium classical thermodynamical theory of phase transition and adsorption in mixtures is proposed. The main assumptions of classical theory are derived as a consequence of the second principle of thermodynamics by introducing a suitable interaction between the bulk phases and the interface.
Influence of the interface on phase transitions in binary mixtures / Iannece, Donatella. - In: INTERNATIONAL JOURNAL OF ENGINEERING SCIENCE. - ISSN 0020-7225. - STAMPA. - 32:11(1994), pp. 1801-1809.
Influence of the interface on phase transitions in binary mixtures
IANNECE, DONATELLA
1994
Abstract
A rigorous reformulation of nonequilibrium classical thermodynamical theory of phase transition and adsorption in mixtures is proposed. The main assumptions of classical theory are derived as a consequence of the second principle of thermodynamics by introducing a suitable interaction between the bulk phases and the interface.File in questo prodotto:
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