Compounds of certain transition metals in which the metals are in high oxidation states are reagents for the epoxidation and dihydroxylation of steroids. In recent years a variety of oxidative synthetic methods have been reported using transition metal compounds, in stoichiometric or catalytic amounts. The preparation of sterols containing oxygenated functions in suitable positions of the steroid nucleus can be accomplished using various reagents such as methyltrioxorhenium-hydrogen peroxide system, ruthenium tetraoxide, osmium tetraoxide and potassium permanganate.
Synthesis of Polyoxygenated Steroids with Transition Metal-Based Oxidants: Methyltrioxorhenium-Hydrogen Peroxide System, Ruthenium Tetraoxide, Osmium Tetraoxide and Potassium Permanganate / Musumeci, Domenica; Sica, Donato; Zollo, Franco. - In: CURRENT ORGANIC SYNTHESIS. - ISSN 1570-1794. - STAMPA. - 2:(2005), pp. 1-20. [10.2174/1570179052996919]
Synthesis of Polyoxygenated Steroids with Transition Metal-Based Oxidants: Methyltrioxorhenium-Hydrogen Peroxide System, Ruthenium Tetraoxide, Osmium Tetraoxide and Potassium Permanganate
MUSUMECI, DOMENICA;SICA, DONATO;ZOLLO, FRANCO
2005
Abstract
Compounds of certain transition metals in which the metals are in high oxidation states are reagents for the epoxidation and dihydroxylation of steroids. In recent years a variety of oxidative synthetic methods have been reported using transition metal compounds, in stoichiometric or catalytic amounts. The preparation of sterols containing oxygenated functions in suitable positions of the steroid nucleus can be accomplished using various reagents such as methyltrioxorhenium-hydrogen peroxide system, ruthenium tetraoxide, osmium tetraoxide and potassium permanganate.File | Dimensione | Formato | |
---|---|---|---|
CurrOrgSynthes2005-PolyoxSteroids_MetalOx.pdf
solo utenti autorizzati
Tipologia:
Documento in Post-print
Licenza:
Accesso privato/ristretto
Dimensione
382.34 kB
Formato
Adobe PDF
|
382.34 kB | Adobe PDF | Visualizza/Apri Richiedi una copia |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.