The absolute stereochemistry of amphilectene metabolites from Cribochalina sp. has been revised by a detailed NMR spectroscopic study of the mosher ester derivatives of a related alcohol. The relative stereochemistry of the previously described amphilectenes has been reinvestigated and reassigned on the basis of the X-ray structural analysis carried out on one of them. The structure of a new amphilectene metabolite, which is an isothiocyanato analogue, is also presented.

Structural and stereochemical revision of isocyanide and isotiocyanate amphilectenes from the caribbean marine sponge Cribochalina sp.

MAZZARELLA, LELIO;
2005

Abstract

The absolute stereochemistry of amphilectene metabolites from Cribochalina sp. has been revised by a detailed NMR spectroscopic study of the mosher ester derivatives of a related alcohol. The relative stereochemistry of the previously described amphilectenes has been reinvestigated and reassigned on the basis of the X-ray structural analysis carried out on one of them. The structure of a new amphilectene metabolite, which is an isothiocyanato analogue, is also presented.
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11588/107389
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