Oxidative addition reactions of Pd(PPh3)4 on the pyrimidine nucleosides 3',5'-di-Oacetylthymidine and 3',5'-di-O-acetyl-4-chlorothymidine and on the nucleobase 1-methylthymine have been investigated. N3 and C4 metal coordinated complexes 3 and 7 were isolated and characterized by spectroscopic techniques. Moreover, the crystal structure of the trans- [PdCl(1-methyl thymine)(PPh3)2]H2O is reported.

REACTIONS OF Pd(PPH3)4 WITH 3',5'-DI-O-ACETYLTHYMIDINE: OXIDATIVE ADDITION OF Pd(PPH3)4 ON THYMIDINE N3 AND C4 ATOMS

ROMANELLI, ALESSANDRA;PICCIALLI, GENNARO;RUFFO, FRANCESCO;DE NAPOLI, LORENZO;PEDONE, CARLO;
2005

Abstract

Oxidative addition reactions of Pd(PPh3)4 on the pyrimidine nucleosides 3',5'-di-Oacetylthymidine and 3',5'-di-O-acetyl-4-chlorothymidine and on the nucleobase 1-methylthymine have been investigated. N3 and C4 metal coordinated complexes 3 and 7 were isolated and characterized by spectroscopic techniques. Moreover, the crystal structure of the trans- [PdCl(1-methyl thymine)(PPh3)2]H2O is reported.
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11588/10711
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