Photooxygenation of non-aromatic heterocycles and cyclic compounds containing non-usual heteroatoms, namely silicon, germanium and tellurium has been reviewed. All three types of photooxygenation (Types I-III) can take place. Moreover the heteroatom can be frequently involved endorsing electron-transfer reactions which turn out to be the main pathways, even in singlet oxygen oxygenation. A vast collection of novel and unexpected products are often formed, sometimes in a stereocontrolled manner.
Photooxygenation of Non-Aromatic Heterocycles / Iesce, MARIA ROSARIA; Cermola, Flavio; M., Rubino. - In: CURRENT ORGANIC CHEMISTRY. - ISSN 1385-2728. - STAMPA. - 11:(2007), pp. 1053-1075.
Photooxygenation of Non-Aromatic Heterocycles
IESCE, MARIA ROSARIA;CERMOLA, FLAVIO;
2007
Abstract
Photooxygenation of non-aromatic heterocycles and cyclic compounds containing non-usual heteroatoms, namely silicon, germanium and tellurium has been reviewed. All three types of photooxygenation (Types I-III) can take place. Moreover the heteroatom can be frequently involved endorsing electron-transfer reactions which turn out to be the main pathways, even in singlet oxygen oxygenation. A vast collection of novel and unexpected products are often formed, sometimes in a stereocontrolled manner.File | Dimensione | Formato | |
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