Four new OH-functionalized orthopalladated complexes bearing an electron-donor and an acceptor group in a trans-like arrangement with respect to the metal have been prepared and characterized. The ligands are Schiff bases, bound as C,N- or N, O-chelating moieties. Four new polyesters were obtained by polycondensation from the monomeric complexes and pentyloxyterephthaloyl chloride. Two "model" complexes, each one related to one monomer, were also synthetized, in order to obtain further and more detailed characterization data, and in particular to perform measurements of mubeta.
New NLO active cyclopalladated chromophores in main-chain polymers / F., Cariati; Caruso, Ugo; Centore, Roberto; DE MARIA, Antonella; M., Fusco; Panunzi, Barbara; Roviello, Antonio; Tuzi, Angela. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - STAMPA. - 357(2):(2004), pp. 548-556.
New NLO active cyclopalladated chromophores in main-chain polymers
CARUSO, UGO;CENTORE, ROBERTO;DE MARIA, ANTONELLA;PANUNZI, BARBARA;ROVIELLO, ANTONIO;TUZI, ANGELA
2004
Abstract
Four new OH-functionalized orthopalladated complexes bearing an electron-donor and an acceptor group in a trans-like arrangement with respect to the metal have been prepared and characterized. The ligands are Schiff bases, bound as C,N- or N, O-chelating moieties. Four new polyesters were obtained by polycondensation from the monomeric complexes and pentyloxyterephthaloyl chloride. Two "model" complexes, each one related to one monomer, were also synthetized, in order to obtain further and more detailed characterization data, and in particular to perform measurements of mubeta.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
